ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Impact of Molecular Structure on Assembly of Microemulsions in Porous Electrodes
Abstract: Microemulsions (ME) have applications in a variety of sectors from food products to pharmaceuticals and healthcare to energy materials, with recent interest in their electrochemical functionality for use in energy-related devices. MEs consist of oil, water, and surfactants that comprise of a hydrophilic head and a hydrophobic tail. From a molecular perspective, their functionality is dependent on the ordering and packing of the surfactant at the oil-water interface. For instance, our recent studies of Tween-20/water/toluene MEs probed the ternary phase diagram with cyclic voltammetry, conductivity, SANS, and NMR. The electrochemical techniques have shown there is facile electron transfer from ferrocene in the oil phase and the electrochemical kinetics are sufficient for use in an energy storage device. Similar studies are underway for the Brij-35/water/toluene system, as both Brij-35 and Tween-20 are non-ionic surfactants with similar structure, except Brij-35 is a linear molecule, while Tween-20 is branched. Thus, the local packing and ordering of Tween-20 at the oil-water interface will differ from that of Brij-35, which in turn may impact ionic transport across the interface. We are interested in understanding how this variation in molecular structure and local packing will impact the mesoscale structure and assembly of the ME and correlate this to its performance in an energy storage device.
Experimenter: Dr Mark Dadmun
Local Contact: Dr Steven Parnell
Experimenter: Dr Adam Imel
Experimenter: Miss Mrinalini Kalyani Ayilliath Kolaprath
DOI: 10.5286/ISIS.E.RB2420168
ISIS Experiment Number: RB2420168
| Part DOI | Instrument | Public release date | Download Link |
|---|---|---|---|
| 10.5286/ISIS.E.RB2420168-1 | LARMOR | 21 December 2027 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr Mark Dadmun et al; (2024): Impact of Molecular Structure on Assembly of Microemulsions in Porous Electrodes, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2420168
