This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
INS Studies of Olefin Reactivity in HZSM-5 Zeolite Catalysts
Abstract: This proposal looks at the reactivity of propene in a commercial ZSM-5 zeolite catalyst. It builds on a previous INS study (on TOSCA) which showed that propene in this catalyst at room temperature forms long chain oligomeric carbenium cations. We will examine what happens to these oligomers when heated to higher temperatures, and what happens when propene is directly admitted to the catalyst at higher temperatures. The measurements will provide understanding of the role of olefin oligomers in the catalytic conversion of methanol to hydrocarbons, and in the conversion of olefins to middle distillate, which are both commercial processes utilising this catalyst.
Principal Investigator: Professor Russell Howe
Experimenter: Dr Ying Li
Experimenter: Ms Shouying Huang
Experimenter: Dr Iain Hitchcock
Experimenter: Professor David Lennon
Experimenter: Professor Stewart Parker
Experimenter: Dr Alexander Hawkins
Experimenter: Ms Andrea Zachariou
DOI: 10.5286/ISIS.E.RB1910203
ISIS Experiment Number: RB1910203
Part DOI | Instrument | Public release date | Download Link |
---|---|---|---|
10.5286/ISIS.E.101133845 | TOSCA | 24 March 2022 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Professor Russell Howe et al; (2019): INS Studies of Olefin Reactivity in HZSM-5 Zeolite Catalysts, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1910203