This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Thermodynamic stability, Na-ion mobility and oxygen deficiency in Na0.7MnO2 P2-type phase
Abstract: The overwhelming majority of mobile applications, ranging from portable consumer electronics to electric cars, currently rely on lithium-ion battery technology. Whilst lithium-based power storage has advantages in terms of high voltage and high gravimetric capacities, there are a number of disadvantages. Sodium-ion batteries have received extensive interest, largely due to the high earth abundance of Na, and are particularly attractive for static energy storage applications for load-balancing of intermittent production of electrical power from (e.g.) solar and wind. This proposal aims to characterise a promising cathode material for future sodium-ion batteries, Na1-xMnO2. The electrochemical performance of Na0.7MnO2-x has been previously related to its defect structure, including cation/vacancy ordering and oxygen non-stoichiometry. However, these studies have relied on X-ray radiation, which is unsuitable for determining light elements' atomic positions and occupancies. We would like to collect neutron powder diffraction data on Polaris as a function of temperature and gas atmosphere for a phase-pure Na0.7MnO2 sample. This will provide important information on the thermodynamic stability of the various phases, the Na-ion mobility and the oxygen deficiency of the material under different conditions.
Experimenter: Dr Jordi Jacas Biendicho
Local Contact: Dr Gabriel Perez
Experimenter: Dr Steve Hull
Experimenter: Mr Sergio Sergio Ramos Lozano
DOI: 10.5286/ISIS.E.RB2510571
ISIS Experiment Number: RB2510571
| Part DOI | Instrument | Public release date | Download Link |
|---|---|---|---|
| 10.5286/ISIS.E.RB2510571-1 | POLARIS | 23 July 2028 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
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Dr Jordi Jacas Biendicho et al; (2026): Thermodynamic stability, Na-ion mobility and oxygen deficiency in Na0.7MnO2 P2-type phase, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2510571
Data is released under the CC-BY-4.0 license.