ISIS Neutron and Muon Source Data Journal

This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.


Investigation of the nuclear and magnetic structure of Na2Mn3O7

Abstract: Layered sodium manganese oxides have attracted extensive attention within the literature due to their potential as electrode materials in battery technologies but additionally the propensity to exhibit exotic magnetic states. The latter arises as a result of the geometrically frustrated connectivity of the magnetic manganese cation which results in not pairwise interactions being satisfied. The layered oxide Na2Mn3O7, is interesting as it has a "Maple Leaf" manganese connectivity resulting in the potential for complex magnetic order. Few investigations have been performed on this material with the vast majority of these focussed on battery cycling experiments. Furthermore, our recent discovery that Na2Mn3O7 readily hydrates under normal conditions also sheds significant doubt on the few measurements available in the literature. To date (that we are aware of) no neutron diffraction data has been collected. As such neither the nuclear nor the magnetic structure of pristine material has been experimentally confirmed. We propose to collect variable temperature powder neutron diffraction data on a material which has been stored in a glove box in order to clarify the room temperature nuclear structure and understand the structural and magnetic behaviour as a function of temperature.

Principal Investigator: Dr Donna Arnold
Experimenter: Mr Elias Djafri
Experimenter: Mr James Beecham-lonsdale
Experimenter: Dr Silvia Ramos
Local Contact: Dr Ivan da Silva Gonzalez

DOI: 10.5286/ISIS.E.RB2310433

ISIS Experiment Number: RB2310433

Part DOI Instrument Public release date Download Link
10.5286/ISIS.E.RB2310433-1 GEM 26 February 2027 Download

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
Select the data format above to find out more about it.

Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Dr Donna Arnold et al; (2024): Investigation of the nuclear and magnetic structure of Na2Mn3O7, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2310433

Data is released under the CC-BY-4.0 license.



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