ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Measuring superexchange in a strongly interacting metal-organic framework magnet
Abstract: Metal-organic framework magnets (MOFMs) are a promising class of magnets due to their tunability, but a historic challenge has been introducing strong enough superexchange interactions for practical applications. Recent work has shown that Cr(II) based magnets can have very strong magnetic interactions through either itinerancy or the generation of radical ligands. We have synthesised a new Cr MOFM without either metallicity or radical ligands with order of magnitude stronger magnetic superexchange than other analogues. In this experiment we will directly measure the superexchange interactions through powder inelastic neutron scattering, allowing us to suggest new avenues for generating strong through-organic-ligand superexchange. Additionally, we will uncover the origin of the significantly suppressed magnetic ordering in this material.
Local Contact: Dr Ross Stewart
Experimenter: Dr Matthew Cliffe
Experimenter: Dr Jem Pitcairn
DOI: 10.5286/ISIS.E.RB2210345
ISIS Experiment Number: RB2210345
| Part DOI | Instrument | Public release date | Download Link |
|---|---|---|---|
| 10.5286/ISIS.E.RB2210345-1 | LET | 07 April 2025 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr Ross Stewart et al; (2022): Measuring superexchange in a strongly interacting metal-organic framework magnet, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2210345
Data is released under the CC-BY-4.0 license.
