This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Phonons under pressure in a barocaloric framework material
Abstract: Conventional vapour-compression refrigeration relies on refrigerants that contribute both to global warming and ozone depletion. Barocaloric materials, in which a large isothermal entropy change is associated with a pressure-induced phase transition, offer an eco-friendly alternative. The framework material TPrAMn(dca)3 has recently been shown to have a giant barocaloric effect, due to an order-disorder phase transition involving both the dca and TPrA ions. Understanding the dynamics of this material under pressure is vital to explaining and optimising this material?s functional behaviour. In this proposal, we aim to do this by measuring the phonon dispersion on MERLIN. Together with our scheduled study of this material?s crystallographic structure on GEM, this will provide a complete picture of this material?s remarkable properties.
Principal Investigator: Dr Anthony Phillips
Experimenter: Miss Bernet Meijer
Local Contact: Dr Helen Walker
Experimenter: Dr Richard Dixey
DOI: 10.5286/ISIS.E.RB2010259
ISIS Experiment Number: RB2010259
Part DOI | Instrument | Public release date | Download Link |
---|---|---|---|
10.5286/ISIS.E.RB2010259-1 | MERLIN | 13 December 2023 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr Anthony Phillips et al; (2020): Phonons under pressure in a barocaloric framework material, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2010259
Data is released under the CC-BY-4.0 license.