ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Ruthenium models of the [FeFe]-hydrogenase active site: seeking the terminal hydride
Abstract: The [FeFe]-hydrogenase enzymes are some of the best catalysts know for generating hydrogen. We have an ongoing programme to understand how their chemistry works, and to replicate the core 'active site' of the enzyme. Recent literature reports have shown that replacing iron by ruthenium in the enzyme can allow isolation of a long sought 'terminal hydride' intermediate. Here, we will seek evidence that this intriguing compound can be seen by muon spectroscopy.
Principal Investigator: Dr Joseph Wright
Local Contact: Dr Stephen Cottrell
Experimenter: Dr Atheer Madlool
DOI: 10.5286/ISIS.E.RB2010219
ISIS Experiment Number: RB2010219
| Part DOI | Instrument | Public release date | Download Link |
|---|---|---|---|
| 10.5286/ISIS.E.RB2010219-1 | HIFI | 07 October 2023 | Download |
| 10.5286/ISIS.E.RB2010219-2 | HIFI | 14 June 2024 | Download |
| 10.5286/ISIS.E.RB2010219-3 | HIFI | 15 June 2024 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr Joseph Wright et al; (2020): Ruthenium models of the [FeFe]-hydrogenase active site: seeking the terminal hydride, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2010219
Data is released under the CC-BY-4.0 license.
