ISIS Neutron and Muon Source Data Journal

Rh(I) in Topochemically Reduced Extended Oxides

Abstract: In recent years there has been a growing interest in modifying the anion lattice of complex transition metal oxides, via topochemical manipulation, to tune the magnetic and electronic properties of these materials. These processes not only alter the electron count of the phase but also the local symmetry and coordination geometry of the transition metal centres. We have utilized low temperature topochemical anion deintercalation reactions to reduce a series of rhodium-containing Ruddlesden-Popper oxides, to yield the first extended oxide phases to contain Rh(I) centres. We propose to collect neutron powder diffraction data to determine the crystal structures of the reduced compounds and the nature of the magnetic ordering present at low temperature.

Principal Investigator: Professor Michael Hayward
Local Contact: Dr Ronald Smith
Experimenter: Miss ZHEYING XU
Experimenter: Mr Subhadip Mallick

DOI: 10.5286/ISIS.E.RB1920388

ISIS Experiment Number: RB1920388

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Michael Hayward et al; (2019): Rh(I) in Topochemically Reduced Extended Oxides, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1920388

Data is released under the CC-BY-4.0 license.