ISIS Neutron and Muon Source Data Journal

Investigation of methanol mobility in zeolite H-ZSM-5 pores as a function of acid site density

Abstract: Zeolites are porous aluminosilicate minerals widely used as adsorbents or catalysts in a myriad of commercial petrochemical and environmental processes including production of transportation fuels (such as gasoline) and exhaust after-treatment of an end-pipe of a mobile (car or truck) or stationary source (industrial chimney). The process involves the diffusion of molecules through the zeolite pores to and from the active sites, which are often Brønsted acidic sites. The diffusion characteristics of the reactants and products determine the reaction kinetics of a reaction. The present study aims to understand the diffusion properties of methanol as a function of Brønsted acidic site density of zeolite H-ZSM-5, which is the part of methanol to gasoline (MTG) process. This information enables us to better understand and tune the MTG activity, product selectivity and catalyst stability.

Principal Investigator: Dr Santhosh Matam
Experimenter: Professor Richard Catlow
Local Contact: Dr Ian Silverwood
Experimenter: Mr David Jurado Apolo

DOI: 10.5286/ISIS.E.RB1920441

ISIS Experiment Number: RB1920441

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Dr Santhosh Matam et al; (2019): Investigation of methanol mobility in zeolite H-ZSM-5 pores as a function of acid site density, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1920441