ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Structure of a barocaloric framework under pressure
Abstract: The barocaloric effect is a promising means of achieving solid-state refrigeration. For this reason, the recent discovery that the coordination framework TPrA[Mn(dca)3] has a “giant” barocaloric coefficient is both scientifically exciting and potentially technologically exploitable. Exploiting this effect will require a detailed understanding of its origin at the atomic scale; yet so far, neither the structure nor the dynamics of this material have been determined under pressure. Here we begin to resolve this situation by proposing a diffraction study on GEM, using a gas cell to investigate the effect of small pressure increments on the structure. Our results will be important in their own right, but will also form the basis of a proposal for EPSRC funding to study these materials’ dynamics via subsequent neutron spectroscopy experiments.
Principal Investigator: Dr Anthony Phillips
Experimenter: Dr Helen Walker
Local Contact: Dr Ivan da Silva Gonzalez
DOI: 10.5286/ISIS.E.RB1820332
ISIS Experiment Number: RB1820332
| Part DOI | Instrument | Public release date | Download Link |
|---|---|---|---|
| 10.5286/ISIS.E.RB1820332-1 | GEM | 24 October 2022 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr Anthony Phillips et al; (2019): Structure of a barocaloric framework under pressure, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1820332
Data is released under the CC-BY-4.0 license.
