ISIS Neutron and Muon Source Data Journal

This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.


Further studies of the ethanol-to-gasoline reaction

Abstract: In our recent beamtime (RB 1820043 TOSCA and RB 1820044 MAPS), we prepared a series of ZSM5 samples that had undergone the ethanol-to-gasoline (ETG) reaction for different times and at different temperatures (200, 300 and 400C for 3 or 168 hours). There is no doubt that the spectra are completely dominated by ethanol. Either the accepted mechanism is misleading and only ethanol is present in any significant amount or we failed to remove excess ethanol at the end of the reaction. We will dry the existing samples under flowing He at elevated temperature for an extended period of time, while monitoring the effluent by mass spectroscopy, until the ethanol signal disappears. If the chemistry is dominated by ethanol, then its removal will leave bare zeolite, else it will reveal the material retained in the pores. Either result is novel.

Principal Investigator: Dr Martin Jones
Experimenter: Miss Changhua Song
Experimenter: Professor Stewart Parker

DOI: 10.5286/ISIS.E.RB1910023

ISIS Experiment Number: RB1910023

Part DOI Instrument Public release date Download Link
10.5286/ISIS.E.RB1910023-1 TOSCA 09 July 2022 Download

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
Select the data format above to find out more about it.

Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Dr Martin Jones et al; (2019): Further studies of the ethanol-to-gasoline reaction, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1910023

Data is released under the CC-BY-4.0 license.



UKRI


Science and Technology Facilities Council Switchboard: 01793 442000