ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Studying the strength of acid sites in an industrial ZSM-5 catalyst: MAPS
Abstract: As part of an on-going programme of work to better understand critical factors in the methanol-to-hydrocarbon process over ZSM-5 zeolite catalysts, it is becoming increasingly important to more precisely describe the nature and form of the active site distribution. This proposal seeks to use the MAPS spectrometer to analyse pyridine chemisorption over ZSM-5 that has experienced specific sample treatments. The MAPS measurements will concentrate on hydroxyl modes (stretch and deformation) associated with Brønsted acidity and the pyridinium N-H stretch modes generated by reaction with pyridine. A linked application for TOSCA time will concentrate on characterising the presence and diminution of pyridinium ion modes as a function of the reaction coordinate.
Principal Investigator: Professor David Lennon
Experimenter: Dr Paul Collier
Experimenter: Ms Andrea Zachariou
Experimenter: Dr Alexander Hawkins
Local Contact: Professor Stewart Parker
DOI: 10.5286/ISIS.E.RB1910561
ISIS Experiment Number: RB1910561
| Part DOI | Instrument | Public release date | Download Link |
|---|---|---|---|
| 10.5286/ISIS.E.RB1910561-1 | MAPS | 03 July 2022 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Professor David Lennon et al; (2019): Studying the strength of acid sites in an industrial ZSM-5 catalyst: MAPS, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1910561
