ISIS Neutron and Muon Source Data Journal

This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.


Probing the electroactive structuring of ionic liquids and their solutions: Effect of water and anion

Abstract: The interfacial structuring of a non-halogenated ionic liquid (IL) will be studied at a gold electrode interface as a function of applied potential, bulk IL concentration and water content. For enhanced sensitivity to changes in the interfacial layers, the scattering length density of the IL mixtures (with propylene carbonate) will be contrast matched to that of the gold. The results will be compared to recent neutron reflectivity (NR) measurements for another IL with the same cation, but a larger, more hydrophobic anion. Complementary atomistic simulations and tribological measurements by our group suggest a significantly different interaction for these two anions and water, thus affecting their lubrication properties. By integration of such knowledge with NR we hope to guide the future application of ILs as ‘tribotronic’ lubricants, as well as in other electrochemical applications.

Principal Investigator: Professor Mark Rutland
Experimenter: Professor Mark Rutland
Experimenter: Professor Sergei Glavatskih
Local Contact: Dr Rebecca Welbourn
Experimenter: Dr Anna Oleshkevych
Experimenter: Dr Georgia Pilkington
Experimenter: Dr Bulat Munavirov
Experimenter: Mr Bhaskar Reddy
Experimenter: Dr Seiya Watanabe
Experimenter: Mr Erik BERGENDAL
Experimenter: Miss Chloe Marie Skingle
Experimenter: Dr Rob Barker

DOI: 10.5286/ISIS.E.RB1910206

ISIS Experiment Number: RB1910206

Part DOI Instrument Public release date Download Link
10.5286/ISIS.E.RB1910206-1 INTER 15 June 2022 Download

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
Select the data format above to find out more about it.

Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Mark Rutland et al; (2019): Probing the electroactive structuring of ionic liquids and their solutions: Effect of water and anion, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1910206

Data is released under the CC-BY-4.0 license.



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