ISIS Neutron and Muon Source Data Journal

This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.


Understanding the decomposition of ammonia by lithium-calcium imide

Abstract: Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data indicate that there are changes in the catalyst composition during the reaction, and thus the precise reaction mechanism remains unclear. Here, we propose to conduct two days of neutron powder diffraction measurements on the POLARIS diffractometer to probe these changes, giving insight to the ammonia decomposition reaction by monitoring the structure of the catalyst during the reaction and examining the data for potential variations in stoichiometry and the extent of isotope exchange in the sample.

Principal Investigator: Professor Bill David
Experimenter: Dr Josh Makepeace
Experimenter: Dr Martin Jones
Experimenter: Dr Hazel Hunter
Local Contact: Dr Ronald Smith
Experimenter: Dr Tom Wood

DOI: 10.5286/ISIS.E.RB1510638

ISIS Experiment Number: RB1510638

Part DOI Instrument Public release date Download Link
10.5286/ISIS.E.67774509 POLARIS 11 November 2018 Download

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
Select the data format above to find out more about it.

Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Bill David et al; (2015): Understanding the decomposition of ammonia by lithium-calcium imide, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1510638

Data is released under the CC-BY-4.0 license.



UKRI


Science and Technology Facilities Council Switchboard: 01793 442000