ISIS Neutron and Muon Source Data Journal

This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.


Aza-crown-stabilized Alkali-Alkalide Systems: Solvent and metal effects on diffusion and methyl group dynamics

Abstract: We request 4 days on IRIS to investigate the diffusional and rotational dynamics of the alkalide forming, fully methylated aza-crown hexamethyl-hexacyclen (HMHC) in solution.Through partial deuteration of HMHC we can isolate these motions, and thus determine the effect of alkalide binding and solvent in two systems (dimethyl ether, isopropylamine).

Principal Investigator: Professor Anthony Barrett
Experimenter: Dr René Riedel
Experimenter: Dr Andrew Seel
Experimenter: Professor Peter Edwards
Local Contact: Dr Victoria Garcia Sakai

DOI: 10.5286/ISIS.E.RB1520413

ISIS Experiment Number: RB1520413

Part DOI Instrument Public release date Download Link
10.5286/ISIS.E.63526428 IRIS 23 September 2018 Download

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
Select the data format above to find out more about it.

Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Anthony Barrett et al; (2015): Aza-crown-stabilized Alkali-Alkalide Systems: Solvent and metal effects on diffusion and methyl group dynamics, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1520413

Data is released under the CC-BY-4.0 license.



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