ISIS Neutron and Muon Source Data Journal

Structural and Magnetic Characterisation of a Novel Magnetic MOF

Abstract: Metal organic framework (MOF) materials are porous solids formed from a network of metal centres mainly coordinated to organic linkers. Examples of magnetic MOFs with strong magnetic interactions as a result of 3D superexchange are rare. We have prepared a new MOF material Fe2F5(Htaz) that realises a 3D inorganic network containing Fe(II) and Fe(III) cations. Magnetic susceptibility indicate the dominance of strong antiferromagnetic correlations within Fe2F5(Htaz) and the system appears to undergo an ordering transition at ~ 100 K to a ferrimagnetic state. We request one day on GEM to investigate the evolution of spin order in this new magnetic MOF material as a function of temperature.

Principal Investigator: Dr Lucy Clark
Experimenter: Professor Jean-Marc Grenèche
Experimenter: Ms Vanessa Pimenta
Experimenter: Dr Jérôme Lhoste
Experimenter: Ms Marjorie Albino
Experimenter: Professor Philip Lightfoot
Experimenter: Dr Marc Leblanc
Experimenter: Professor Vincent Vincent Maisonneuve
Experimenter: Dr Annie Hémon-Ribaud

DOI: 10.5286/ISIS.E.RB1510102

ISIS Experiment Number: RB1510102

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Dr Lucy Clark et al; (2015): Structural and Magnetic Characterisation of a Novel Magnetic MOF, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1510102