This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Modelling the Structure of Metal-organic Framework Glasses
Abstract: We have recently demonstrated the glass-forming ability of the family of hybrid micro-porous materials known as metal-organic frameworks (MOFs). Specifically, a family known as zeolitic imidazolate frameworks (ZIFs), consisting of Zn2+ ions linked by imidazolate (C3H3N2-) based organic ligands, melt upon heating in argon, and their liquids can be quenched to form glasses with a tetrahedral metal-ligand-metal connectivity. Here we propose to use netron total scattering to probe the structure of one example of a glass formed by such a route. Furthermore, we wish to investigate the relationship between this structure, and the same MOF ball-milled.
Principal Investigator: Dr Tom Bennett
Experimenter: Professor David Keen
DOI: 10.5286/ISIS.E.RB1610014
ISIS Experiment Number: RB1610014
Part DOI | Instrument | Public release date | Download Link |
---|---|---|---|
10.5286/ISIS.E.73941840 | GEM | 03 March 2019 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
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publication is as:
[author], [date], [title], [publisher],
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For Example:
Dr Tom Bennett et al; (2016): Modelling the Structure of Metal-organic Framework Glasses, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1610014
Data is released under the CC-BY-4.0 license.