ISIS Neutron and Muon Source Data Journal

INS Studies of Porous Metal-Organic Framework Materials for High Capacity Gas Adsorption

Abstract: We seek to develop highly robust MOF materials as high capacity gas storage systems and request 12 days on TOSCA to study the binding interaction between adsorbed gas molecules (CO2/C2H2/C2H4/C2H6/C3H6/C3H8) and three isostructural MOFs incorporating different functional groups as a function of gas loading. This proposed study will investigate the vibrational properties exhibited by both adsorbed gas substrates (except for CO2 due to the low neutron scattering cross sections) and the porous hosts. MFM-102-NO2 exhibit exceptionally high storage capacity for CO2 and light hydrocarbons at ambient conditions with fully reversible uptake, suggesting the presence of specific guest-host interaction.

Principal Investigator: Professor Sihai Yang
Experimenter: Dr Svemir Rudic
Experimenter: Mr Harry Godfrey
Experimenter: Miss Lydia Briggs
Experimenter: Dr Shaojun Xu
Experimenter: Mr Joe Carter
Experimenter: Professor Stewart Parker
Experimenter: Dr Jiangnan Li
Experimenter: Professor Martin Schroder

DOI: 10.5286/ISIS.E.RB1720216

ISIS Experiment Number: RB1720216

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Sihai Yang et al; (2017): INS Studies of Porous Metal-Organic Framework Materials for High Capacity Gas Adsorption , STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1720216

Data is released under the CC-BY-4.0 license.