ISIS Neutron and Muon Source Data Journal

HIFI STUDY OF THE HETEROMETALLIC POLYMERS {[{(PTA)2CpRu-μ-CN-RuCp(PTA)2}-μ-CdCl3-]}n, {[{(PTA)2CpRu-μ-CN-RuCp(PTA)2}-μ-LaCl3-]}n and {[{(PTA

Abstract: Our ability to control the synthesis of this kind of material has led to the development of a family of Ru-Ru-M-backbone organometallic compounds with general formula {[(PTA)2CpRu-μ-X-RuCp(PTA)2-μ-MCl3}n (X = CN-, SCN-; M = Au [2], Ni[3], Cd[4], Co[5]...). Our previous Xpress work with the polymers with X=CN-, SCN- and M = Cd, La, clearly demonstrates the muon has the potential to differentiate differences between structurally different ORGANOMETALLIC POLYMERS on the microscopic level. However, it raises several questions; in particular the exact nature of muonium addition in these materials and the influence of the SCN or CN linkage, as well as the magnetic inclusion, on the coupling behaviour. To answer these questions we therefore ask for time on the HiFi spectrometer to complete this study.

Principal Investigator: Professor Antonio Romerosa Nievas
Experimenter: Dr Mark Telling
Experimenter: Dr Franco Scalambra

DOI: 10.5286/ISIS.E.RB1720074

ISIS Experiment Number: RB1720074

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Antonio Romerosa Nievas et al; (2017): HIFI STUDY OF THE HETEROMETALLIC POLYMERS {[{(PTA)2CpRu-μ-CN-RuCp(PTA)2}-μ-CdCl3-]}n, {[{(PTA)2CpRu-μ-CN-RuCp(PTA)2}-μ-LaCl3-]}n and {[{(PTA, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1720074

Data is released under the CC-BY-4.0 license.