ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Temperature dependence of the hydrogen dynamics in an Iridium-hydride complex
Abstract: Transition metal hydrides are critically involved in many stoichiometric and catalytic organometallic reactions, such as hydrogenation. In these reactions a crucial step is the coordination of an intact H2 molecule to the metal centre and the ligand dynamics of the resulting coordination compound. We propose to investigate the temperature dependence of the Anisotropic Displacement Parameters obtained from multi-temperature single-crystal neutron diffraction on the octahedral complex trans-(P iPr3)2IrIH2(H2), in order to get valuable insight on the motion of the hydrogen atoms attached to the metal and consequently on the nature of the H/H2 exchange process and the H2 absorption/desorption process.
Principal Investigator: Dr Silvia Capelli
Local Contact: Dr Fabio Orlandi
Experimenter: Professor Alberto Albinati
DOI: 10.5286/ISIS.E.RB1810850
ISIS Experiment Number: RB1810850
| Part DOI | Instrument | Public release date | Download Link |
|---|---|---|---|
| 10.5286/ISIS.E.92922452 | WISH | 07 May 2021 | Download |
| 10.5286/ISIS.E.95665247 | WISH | 23 June 2021 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
Select the data format above to find
out more about it.
Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr Silvia Capelli et al; (2018): Temperature dependence of the hydrogen dynamics in an Iridium-hydride complex, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1810850
Data is released under the CC-BY-4.0 license.
