This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Conduction Pathways in Alkali Lanthanide Pyrosilicates, A3LnSi2O7
Abstract: Alkali Lanthanide Pyrosilicates (general formula = A3LnSi2O7) are promising candidates for use as solid electrolytes in all solid state Li-ion and Na-ion batteries. To date the structure of Li3LnSi2O7 has not been reported. We have synthesized powder samples of A3LnSi2O7 (A = Li, Na; Ln = Gd-Er) and characterized them by powder X-ray diffraction and impedance spectroscopy. For a full analysis of the crystal structure of A3LnSi2O7, we require neutron powder diffraction to determine the position of the Li, Na, Si, and O atoms in the presence of the heavy Ln atoms; and neutron total scattering to study the effect of alkali ion site disorder on the alkali ion conduction mechanisms in the lanthanide silicate framework.
Principal Investigator: Professor Sian Dutton
Experimenter: Mr Joshua Lewis
Experimenter: Miss Paromita Mukherjee
Experimenter: Mr James Patchett
Local Contact: Dr Helen Playford
Experimenter: Mr Jack Hodkinson
DOI: 10.5286/ISIS.E.RB1810476
ISIS Experiment Number: RB1810476
Part DOI | Instrument | Public release date | Download Link |
---|---|---|---|
10.5286/ISIS.E.90599920 | POLARIS | 12 March 2021 | Download |
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Professor Sian Dutton et al; (2018): Conduction Pathways in Alkali Lanthanide Pyrosilicates, A3LnSi2O7, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1810476
Data is released under the CC-BY-4.0 license.