ISIS Neutron and Muon Source Data Journal

The magnetic structure of a perovskite like coordination polymer {[Cu(HCOO)3]H2N(CH3)2}n

Abstract: This study is designed to identify relationships between structure and magnetic properties characteristic of coordination polymers (CPs). By determining the ground state 3D magnetic structure of {[Cu(HCOO)3]H2N(CH3)2}n, a CP exhibiting quasi-1D magnetism despite a 3D covalent structure, we will be able to address the factors that regulate the strength and nature of the super-exchange magnetic couplings, as well as correlation between the orientation of the magnetic moments and crystal-field anisotropy produced by the Jahn-Teller effect. To achieve this goal the unique information retrieved from powder neutron diffraction as a function of temperature will be compared with the results of DFT simulations, experimental charge density analysis, and magnetic susceptibility.

Principal Investigator: Dr Roger Johnson
Experimenter: Dr Robert Williams
Experimenter: Dr Paul Goddard
Experimenter: Mr Sam Curley
Local Contact: Dr Pascal Manuel
Experimenter: Dr Rebecca Scatena

DOI: 10.5286/ISIS.E.RB1910039

ISIS Experiment Number: RB1910039

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Dr Roger Johnson et al; (2019): The magnetic structure of a perovskite like coordination polymer {[Cu(HCOO)3]H2N(CH3)2}n , STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1910039

Data is released under the CC-BY-4.0 license.