This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Investigation of the ligand interaction in thiol-capped Au and Pd nanoparticle catalysts
Abstract: Organic stabilisers, such as thiols, thioethers, amines and polymers (i.e. polyvinylalcohol) have been used for the stabilisation of metal nanoparticles. The catalytic performance of polymer- and thiol- capped metallic nanoparticles has been explored and it has been found that apart from the morphological characteristics of the inorganic nanoparticle, the catalytic activity increases when the reactant gets closer to the nanoparticle surface. Thus, the structure and configuration of the surface ligands can play a critical role in catalysis because they determine the accessibility of the reactant to the nanoparticle surface. INS spectroscopy will help us to extract reliable information about the influence of ligand capping in catalysis.
Public release date: 09 October 2016
Principal Investigator: Professor Richard Catlow
Experimenter: Professor Stewart Parker
Experimenter: Dr Peter Wells
Experimenter: Dr Nikolaos Dimitratos
Experimenter: Dr Antonios Kanaras
Experimenter: Ms Catherine Brookes
Experimenter: Mr Wilm Jones
DOI: 10.5286/ISIS.E.24091117
ISIS Experiment Number: RB1310090
Part Number: 1 - TOSCA
Date of Experiment: 07 October 2013
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
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Professor Richard Catlow et al; (2013): Investigation of the ligand interaction in thiol-capped Au and Pd nanoparticle catalysts, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.24091117