ISIS Data Journal

The archive for ISIS research data


RB1120410

Investigation title: Polycarbonate and tetramethyl bisphenol A polycarbonate.

Release date: Mon Mar 09 08:28:08 GMT 2015

Creator: Dr Joao Cabral
Creator: Dr Victoria Garcia Sakai
Creator: Dr Valeria Arrighi
Creator: Mr Him Wong
Creator: Mr Carlos Gonzalez Lopez

DOI: 10.5286/ISIS.E.24088149

Date of Experiment: Thu Mar 01 10:21:33 GMT 2012

Publisher: STFC ISIS Facility

Data format: RAW/Nexus
Select the data format above to find out more about it.

Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Dr Joao Cabral et al; (2012): 1120410, STFC ISIS Facility, doi:10.5286/ISIS.E.24088149

Abstract

The miscibility of polycarbonates (PC) with polystyrene (PS) appears to be closely related to chain dynamics. Among all polycarbonates, tetramethyl bisphenol-A polycarbonate (TMPC), is the only PC miscible with PS. The presence of the two methyl groups attached to each phenyl ring, hinder phenyl flips and this may be partly responsible for the formation of miscible blends with PS. The aim of the proposed experiment is to improve our understanding of molecular dynamics of polycarbonates (BPA-PC and TMPC). We also wish to investigate the changes in the motion of TMPC when blended with PS (deuterated).


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