ISIS Neutron and Muon Source Data Journal

An INS investigation on the effect of a regeneration cycle for post-reaction Fe-modified ZSM5 catalysts applied to xylene isomerisation reactions (MAPS)

Abstract: The global demand for p-xylene production is considerable. One production route involves the use of ZSM5 zeolites to affect the isomerisation of m-xylene to p-xylene. However, catalyst deactivation constitutes a significant impediment to the process operation. In partnership with a major catalyst manufacturer (Johnson Matthey), this application seeks to use the MAPS spectrometer to examine the effect of a regeneration cycle on a series of new Fe-doped ZSM5 catalyst formulations under development. Carbon deposition as a function of time-on-stream results in a significant reduction of activity, necessitating the zeolite to experience an oxidative treatment to burn off the ?coke?. Laboratory testing has established that discrete Fe loadings can induce ?soft? coke formation (reversible via regeneration) over ?hard? coke (irreversible). However, the durability of the Fe-doped catalysts with respect to the regeneration treatment is uncertain. MAPS beamtime is requested to analyse a selection of post-reaction samples after a regeneration stage. This procedure will provide spectral insight as to how the regeneration stage perturbs the catalysts? acid site distribution, with particular emphasis on strong Brønsted acid sites. Further measurement of the samples after a second reaction sequence will be used to speciate the form of the hydrocarbonaceous species that results post-regeneration. This MAPS application is linked to an associated TOSCA proposal.

Public release date: 25 February 2028

Principal Investigator: Professor David Lennon
Experimenter: Dr Andrew York
Local Contact: Dr Hamish Cavaye
Experimenter: Professor Stewart Parker
Experimenter: Mr Christos Ballas

DOI: 10.5286/ISIS.E.RB2420046-1

Parent DOI: 10.5286/ISIS.E.RB2420046

ISIS Experiment Number: RB2420046

Part Number: 1

Date of Experiment: 21 February 2025

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor David Lennon et al; (2025): An INS investigation on the effect of a regeneration cycle for post-reaction Fe-modified ZSM5 catalysts applied to xylene isomerisation reactions (MAPS), STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2420046-1

Data is released under the CC-BY-4.0 license.