ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Characterisation of lithium copper hydrides - TOSCA
Abstract: Copper hydride chemical reduction of carbonyl derivatives is a very useful tool in synthetic organic chemistry. This chemistry evolved from fundamental investigations of the simplest possible copper hydride: Cu(I)H . ?Simple? copper hydrides are very scarce. The only known systems are: (i) CuH, (ii) Ba7Cu3H17 (which contains [CuH4]3? and H? ions), (iii) Zr2CuD~5 (limiting composition: 2Zr2+ [Cu+D3]2? 2D?) and (iv) LixCuyH(x+y) ( known for (x,y) = (1,1), (2,1), (3,1), (4,1), (5,1), (1,2), (2,3) [7]). (i) ? (iii) have all been structurally characterised by neutron diffraction, (iv) has not, however, there is no spectroscopic data for any of them and that is the subject of this proposal.
Public release date: 02 May 2024
Experimenter: Dr James Tellam
Local Contact: Professor Stewart Parker
Experimenter: Dr Sabrina Gaertner
DOI: 10.5286/ISIS.E.RB2010041-2
Parent DOI: 10.5286/ISIS.E.RB2010041
ISIS Experiment Number: RB2010041
Part Number: 2
Date of Experiment: 30 April 2021
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr James Tellam et al; (2021): Characterisation of lithium copper hydrides - TOSCA, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB2010041-2
Data is released under the CC-BY-4.0 license.
