ISIS Neutron and Muon Source Data Journal

Magnetic order in the first hybrid layered fluoroperovskites

Abstract: Layered perovskites are well known functional materials but, in the context of fluoride chemistry, have so far been restricted to purely inorganic examples: K2NiF4 is the classic example. On the contrary, hybrid perovskites (i.e. those containing organic moieties between inorganic layers) are currently revolutionising the field of solar cells materials, with the development of hybrid layered lead iodides. There are no fluoride-containing examples. We have recently prepared the first examples of a family of layered perovskite fluorides incorporating organic inter-layer species. We expect these compounds to be of interest for their magnetic properties, rather than optical-based properties. Here we aim to study the magnetic ordering in the first examples of this new family. In particular, we'll look at a new hybrid cobalt fluoride, which shows a large, reversible magnetisation below ~ 80 K

Public release date: 12 February 2023

Principal Investigator: Professor Philip Lightfoot
Experimenter: Mr Alasdair Bradford
Experimenter: Dr Jason McNulty
Local Contact: Dr Ivan da Silva Gonzalez
Experimenter: Professor Stephen Lee
Experimenter: Mr Teng Li

DOI: 10.5286/ISIS.E.RB1920072-1

Parent DOI: 10.5286/ISIS.E.RB1920072

ISIS Experiment Number: RB1920072

Part Number: 1

Date of Experiment: 16 December 2019

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
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Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Philip Lightfoot et al; (2019): Magnetic order in the first hybrid layered fluoroperovskites, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1920072-1

Data is released under the CC-BY-4.0 license.