ISIS Neutron and Muon Source Data Journal
This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Low-temperature structures of Prussian blue analogues for electrochemical applications
Abstract: We propose a low-temperature diffraction study at POLARIS of Prussian blue analogues (PBAs) of general formula NaxMM'(CN)6, where 1 < x 2. These systems currently attract intense research interest due to their potential applications as electrodes in sodium ion batteries. In order to fully understand the electrochemical processes, accurate structural models are vital. At present, the most favourable position of Na in the framework is debated and we believe that this diffraction study will be an important contribution to this discussion. Moreover, high Na content yields distortions of the metal-cyanide framework---analogous to octahedral tilting in perovskites. We aim to investigate the thermal response of the tilting, which currently is an underexplored area, in contrast to the work on tilting in perovskites. Our study is thus relevant to both applied and fundamental chemistry.
Public release date: 18 November 2022
Principal Investigator: Dr Hanna Boström
Local Contact: Dr Ronald Smith
Experimenter: Dr William Brant
DOI: 10.5286/ISIS.E.RB1920010-1
Parent DOI: 10.5286/ISIS.E.RB1920010
ISIS Experiment Number: RB1920010
Part Number: 1
Date of Experiment: 15 November 2019
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
The recommended format for citing this dataset in a research
publication is as:
[author], [date], [title], [publisher],
[doi]
For Example:
Dr Hanna Boström et al; (2019): Low-temperature structures of Prussian blue analogues for electrochemical applications, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.RB1920010-1
Data is released under the CC-BY-4.0 license.
